The Science of Sugar: How Different Sugars Affect Your Bakes

A clear glass jar filled with sugar cubes next to stacked cubes on a white background.

Sugar does a lot more than just make things sweet.

In baking, sugar plays a crucial role in texture, moisture, color, and even rise. Choosing the right type of sugar—or substituting it without knowing how it works—can totally change the outcome of your dessert.

In this post, we’ll break down the most common types of sugar, how they behave in baking, and when to use each one. By understanding the science behind sugar, you’ll start baking with more confidence—and more consistency.



1. Granulated White Sugar (Table Sugar)

What it is:
Refined, pure sucrose. It’s the most common sugar in baking.


How it affects your bake:

  • Adds sweetness

  • Helps baked goods brown via caramelization

  • Aerates batters when creamed with butter (important for cakes and cookies)

  • Contributes to crispness in cookies

When to use it:
Standard for cakes, cookies, muffins, and anywhere the recipe calls for “sugar.”



2. Brown Sugar (Light & Dark)

What it is:
White sugar with molasses added back in.

  • Light brown sugar = ~3.5% molasses

  • Dark brown sugar = ~6.5% molasses

How it affects your bake:

  • Adds moisture due to the molasses

  • Gives baked goods a soft, chewy texture

  • Adds deeper, caramel-like flavor

  • Can affect color (darker baked goods)

When to use it:
Ideal for chewy cookies, banana bread, gingerbread, and moist cakes.



3. Powdered Sugar (Confectioners’ Sugar)

What it is:
Finely ground white sugar with a bit of cornstarch to prevent clumping.


How it affects your bake:

  • Dissolves quickly in liquids

  • Creates smooth, silky frostings and icings

  • Not ideal for creaming (doesn’t trap air well)

When to use it:
For frostings, buttercream, glazes, dusting, or no-bake desserts.



4. Turbinado Sugar (Raw Sugar)

What it is:
Partially refined sugar with large, golden crystals and mild molasses flavor.


How it affects your bake:

  • Adds crunch and sparkle as a topping

  • Doesn’t dissolve easily, so not great as a direct substitute for white sugar

When to use it:
Sprinkled on muffins, pies, or cookies before baking for texture and visual appeal.



5. Coconut Sugar

What it is:
Made from the sap of coconut palm trees. It’s less processed and has a lower glycemic index than white sugar.


How it affects your bake:

  • Adds a caramel/maple-like flavor

  • Doesn’t cream well with butter

  • Can make baked goods denser or darker

When to use it:
Healthier dessert alternatives, paleo or natural baking, or recipes where a deeper flavor works (like brownies or spice cakes).



6. Liquid Sweeteners (Honey, Maple Syrup, Agave)

What they are:
Unrefined or semi-refined natural sweeteners in liquid form.


How they affect your bake:

  • Add moisture

  • Often lower in sweetness than sugar

  • Can affect structure (because they’re liquids)

  • Impact browning and flavor

When to use them:
In recipes specifically designed for liquid sweeteners, or when adjusting the dry-to-wet ratio to compensate.

Pro Tip: If subbing for white sugar:

  • Use ¾ cup liquid sweetener for every 1 cup of sugar

  • Reduce other liquids by ~2 tablespoons


Why Sugar Affects Texture, Not Just Taste

Sugar doesn’t just sweeten—here’s what it really does:

  • Moisture Retention: Sugar is hygroscopic (it holds water), keeping baked goods soft and moist.

  • Structure & Spread: It weakens gluten (for tender cakes) and contributes to cookie spread.

  • Caramelization: Helps baked goods brown and develop flavor.

  • Fermentation: In yeast breads, sugar feeds the yeast to help dough rise.


⚖️ Can You Substitute One Sugar for Another?

Yes, but it’s not a 1:1 flavor or function match.

Here’s a quick guide:

SubstituteForAdjustment Needed
Brown sugarWhite sugarAdds moisture & deeper flavor
Coconut sugarBrown/white sugarMay require extra leavening
Powdered sugarGranulated sugarOnly in frostings—not good for creaming
Maple syrupWhite sugarReduce liquids in recipe by 2 tbsp per cup
📌 Final Thoughts

Sugar is a foundational ingredient in baking, and understanding its role can take your desserts from good to unforgettable. Whether you’re after chewy, crispy, moist, or fluffy, the type of sugar you use truly matters.